Software for Windows
Free software I recommend for use with Windows.
Business
Openoffice.org (office suite)
Internet
Firefox (web browser)
Nvu (web authoring system, a.k.a. html page editor)
or, the community version KompoZer until the new version of Nvu is released
Thunderbird (email client)
Multimedia
Media player classic
Quicktime alternative codec
System
Synergy (control one or more *nix/Windows machines with just the local keyboard/mouse)
Virtual Dimension (get virtual desktops on Windows just like the desktops running on *nix)
Sandboxie, run programs in a sandbox for extra safety
Utilities
ATnotes (create notes on the desktop)
CDBurnerXP pro
Izarc (compression utility with support for zip, rar, etcetera)